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Enhanced activity of bimetallic Fe-Cu catalysts supported on ceria toward water gas shift reaction: synergistic

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1962-1972 doi: 10.1007/s11705-023-2359-z

摘要： Within the “hydrogen chain”, the high-temperature water gas shift reaction represents a key step to improve the H2 yield and adjust the H2/COx ratio to fit the constraints of downstream processes. Despite the commercial application of the high-temperature water gas shift, novel catalysts characterized by higher intrinsic activity (especially at low temperatures), good thermal stability, and no chromium content are needed. In this work, we propose bimetallic iron-copper catalysts supported on ceria, characterized by low active phase content (iron oxide + copper oxide < 5 wt %). Fresh and used samples were characterized by inductively coupled plasma mass spectrometry, X-ray diffraction, nitrogen physisorption, scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, and temperature programmed reduction in hydrogen to relate physicochemical features and catalytic activity. The sample with iron/copper ≈ 1 and 4 wt % active phase content showed the best catalytic properties in terms of turnover frequency, no methane formation, and stability. Its unique properties were due to both strong iron-copper interaction and strong metal-support interaction, leading to outstanding redox behavior.

关键词： water gas shift     iron     copper     bimetallic catalysts     ceria     hydrogen    

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Catalytic performance of Co-Mo-Ce-K/γ-Al

Yuqiong ZHAO, Yongfa ZHANG

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 457-460 doi: 10.1007/s11705-010-0524-7

摘要： The catalytic performance of Co-Mo-Ce-K/γ-Al O catalyst for the shift reaction of CO in coke oven gas is investigated using X-ray diffraction (XRD) and temperature-programmed reduction (TPR). The results indicate that Ce and K have a synergistic effect on promoting the catalytic activity, and the Co-Mo-Ce-K/γ-Al O catalyst with 3.0 wt-% CeO and 6.0 wt-% K O exhibits the highest activity. CeO favors Co dispersion and mainly produces an electronic effect. TPR characterization results indicate that the addition of CeO -K O in the Co-Mo-Ce-K/γ-Al O catalyst decreases the reduction temperature of active components, and part of octahedrally coordinated Mo transforms into tetrahedrally coordinated Mo , which has a close relationship with the catalytic activity.

关键词： coke oven gas     water gas shift reaction     sulfur-tolerant catalyst     cerium dioxide    

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Effect of adjusted mesoscale drag model on flue gas desulfurization in powder-particle spouted beds

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 909-920 doi: 10.1007/s11705-021-2100-8

摘要： An energy minimum multiscale model was adjusted to simulate the mesoscale structure of the flue gas desulfurization process in a powder-particle spouted bed and verified experimentally. The obtained results revealed that the spout morphology simulated by the adjusted mesoscale drag model was unstable and discontinuous bubbling spout unlike the stable continuous spout obtained using the Gidaspow model. In addition, more thorough gas radial mixing was achieved using the adjusted mesoscale drag model. The mass fraction of water in the gas mixture at the outlet determined by the heterogeneous drag model was 1.5 times higher than that obtained by the homogeneous drag model during the simulation of water vaporization. For the desulfurization reaction, the experimental desulfurization efficiency was 75.03%, while the desulfurization efficiencies obtained by the Gidaspow and adjusted mesoscale drag models were 47.63% and 75.08%, respectively, indicating much higher accuracy of the latter technique.

关键词： adjusted mesoscale drag model     particle image velocimetry     water vaporization     desulfurization reaction     numerical simulation    

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Seasonal microbial community shift in a saline sewage treatment plant

Qingmei YAN, Xuxiang ZHANG, Tong ZHANG, Herbert H P FANG

《环境科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 40-47 doi: 10.1007/s11783-011-0304-8

摘要： Activated sludge was monthly sampled from a saline sewage treatment plant of Hong Kong (China) during June 2007 to May 2008 to analyze the microbial community shift along with environmental variations using denaturing gradient gel electrophoresis of polymerase chain reaction amplified 16S rDNA fragments. Environmental changes resulted into a seasonal microbial community shift characterized by alterations in species number and abundance in the sewage treatment plant. Correspondence analysis and cluster analysis on community structure profile showed that the 12 monthly samples fell into four groups, which is in accordance with season changing in Hong Kong. Canonical correspondence analysis revealed that and posed more significant effects on community structure than total phosphorus and total nitrogen, respectively. Compared with sludge retention time, influent total phosphorus had an inverse effect on the community structure shift, and chemical oxygen demand and showed a similar effects. Results of this study may contribute to the development of new knowledge involving the microbial community shift in sewage treatment plants.

关键词： sewage treatment plants     polymerase chain reaction (PCR)     denaturing gradient gel electrophoresis (DGGE)     canonical correspondence analysis     correspondence analysis    

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Potential shift of bacterial community structure and corrosion-related bacteria in drinking water distributionpipeline driven by water source switching

Yue Hu, Ding Dong, Kun Wan, Chao Chen, Xin Yu, Huirong Lin

《环境科学与工程前沿（英文）》 2021年 第15卷 第2期 doi: 10.1007/s11783-020-1320-3

摘要： Abstract • Bacterial release from aged pipe sections under extreme conditions was quantified. • Released bacterial community structure exhibited large variation after transition. • Risks from transition reduced significantly with cleaner source. As a result of pollution in the present water sources, cities have been forced to utilize cleaner water sources. There are few reports regarding the potential shift of bacterial community structure driven by water source switching, especially that of corrosion-related bacteria. Three types of finished water were used for simulation, the polluted source water from the Qiantang and Dongtiaoxi Rivers (China) was replaced by cleaner water from Qiandao Lake (China). Here, we discussed the transition effects through three simulated reactors. The bacterial characteristics were identified using the high-throughput sequencing and heterotrophic plate count method. It was observed that the level of culturable bacteria declined by 2–3 orders of magnitude after water source switching. The bacterial community released from the pipeline reactor was significantly different under different finished water, and it exhibited large variation at the genus level. Porphyrobacter (58.2%) and Phreatobacter (14.5%) clearly replaced Novosphingobium, Aquabacterium, and Cupriavidus as new dominant genera in system A, which could be attributed to the lower carbon and nitrogen content of the new water source. Although corrosion-inhibiting bacteria decreased after switching, they still maintained dominant in three reactors (6.6%, 15.9%, and 19.7%). Furthermore, potential opportunistic pathogens such as Sphingomonas were detected. Our study shows that after transition to a high quality water source, the total culturable bacteria released was in a downtrend, which leads to a great reduction in the risk of bacterial leakage in the produced drinking water.

关键词： Drinking water biosafety     Water source switching     Drinking water distribution system     Transition effects     High-throughput sequencing    

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Kinetics of pozzolanic reaction for preparation of flue gas desulfurizer from fly ash and Ca(OH)2

WANG Jingang, HU Jinbang, WANG Daobin, DUAN Zhenya

《化学科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 266-270 doi: 10.1007/s11705-007-0048-y

摘要： A kinetic model of the pozzolanic reaction for the preparation of flue gas desulfurizers from fly ash and Ca(OH) was deduced on the basis of solid phase reaction kinetic theory. Kinetic expressions and parameters were obtained and verified by experiment. A comparison of calculated results with experimental results showed that precision in kinetic expressions was good. The apparent reaction rate constants of the pozzolanic reaction could be raised by increasing the specific surface area of fly ash and the hydration temperature, and by using a suitable additive.

关键词： comparison     calculated     pozzolanic reaction     precision     preparation    

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NO conversion by positive streamer discharge—effects of gas compositions and reaction conditions

HE Wei, ZHU Tianle, LI Jing

《环境科学与工程前沿（英文）》 2007年 第1卷 第2期   页码 153-158 doi: 10.1007/s11783-007-0027-z

摘要： The effects of gas compositions and reaction conditions on NO conversion by positive streamer discharge were experimentally investigated by using a link tooth wheel-cylinder reactor. The results showed that NO conversion increased w

关键词： conversion     streamer discharge     wheel-cylinder     positive streamer    

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route to achieve MoSe-NiSe on nickel foam as efficient dual functional electrocatalysts for overall water

《能源前沿（英文）》 2022年 第16卷 第3期   页码 483-491 doi: 10.1007/s11708-022-0813-0

摘要： Since the catalytic activity of present nickel-based synthetic selenide is still to be improved, MoSe2-Ni3Se2 was synthesized on nickel foam (NF) (MoSe2-Ni3Se2/NF) by introducing a molybdenum source. After the molybdenum source was introduced, the surface of the catalyst changed from a single-phase structure to a multi-phase structure. The catalyst surface with enriched active sites and the synergistic effect of MoSe2 and Ni3Se2 together enhance the hydrogen evolution reactions (HER), the oxygen evolution reactions (OER), and electrocatalytic total water splitting activity of the catalyst. The overpotential of the MoSe2-Ni3Se2/NF electrocatalyst is only 259 mV and 395 mV at a current density of 100 mA/cm2 for HER and OER, respectively. MoSe2-Ni3Se2/NF with a two-electrode system attains a current density of 10 mA/cm2 at 1.60 V. In addition, the overpotential of HER and OER of MoSe2-Ni3Se2/NF within 80000 s and the decomposition voltage of electrocatalytic total water decomposition hardly changed, showing an extremely strong stability. The improvement of MoSe2-Ni3Se2/NF catalytic activity is attributed to the establishment of the multi-phase structure and the optimized inoculation of the multi-component and multi-interface.

关键词： three-dimensional molybdenum nanomaterials     hydrogen evolution reaction     oxygen evolution reaction     overall water splitting    

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Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 139-144 doi: 10.1007/s11705-013-1323-8

摘要： Coker gas oil (CGO) is a poor-quality feedstock for fluidized bed catalytic cracking (FCC) or hydrocracking. The pretreatment of CGO, especially hydrotreating, can significantly improve the product quality and protect the catalyst. In this work, we studied the hydrodesulfurization (HDS) of CGO in a slurry reactor. All the experiments were carried out in an autoclave using a NiMo/Al O catalyst at reaction temperature 340°C–400°C, pressure 6–10 MPa, and stirring speed 800 r·min , with hydrogen-to-oil ratio in the range of 500–1500. The effects of the operating parameters on the desulfurization ratio were investigated and discussed. A macro reaction kinetic model was established for the HDS of CGO in the slurry reactor.

关键词： coker gas oil     hydrodesulfurization     slurry reactor     reaction kinetic model    

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Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

Jiajun CHEN , Hao WANG , Na ZHANG ,

《环境科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 313-319 doi: 10.1007/s11783-009-0025-4

摘要： This investigation was carried out to establish a new domestic landfill gas (LFG) generation rate model that takes into account the impact of leachate recirculation. The first-order kinetics and two-stage reaction (FKTSR) model of the LFG generation rate includes mechanisms of the nutrient balance for biochemical reaction in two main stages. In this study, the FKTSR model was modified by the introduction of the outflow function and the organic acid conversion coefficient in order to represent the in-situ condition of nutrient loss through leachate. Laboratory experiments were carried out to simulate the impact of leachate recirculation and verify the modified FKTSR model. The model calibration was then calculated by using the experimental data. The results suggested that the new model was in line with the experimental data. The main parameters of the modified FKTSR model, including the LFG production potential (), the reaction rate constant in the first stage (), and the reaction rate constant in the second stage () of 64.746 L, 0.202 d, and 0.338 d, respectively, were comparable to the old ones of 42.069 L, 0.231 d, and 0.231 d. The new model is better able to explain the mechanisms involved in LFG generation.

关键词： landfill gas (LFG)     generation rate model     first-order kinetics     two-stage reaction     outflow function    

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The impact of different voltage application modes on biodegradation of chloramphenicol and shift of microbial

《环境科学与工程前沿（英文）》 2022年 第16卷 第11期 doi: 10.1007/s11783-022-1576-x

摘要：

● Presented coupled system enhanced biodegradation of antibiotic chloramphenicol.

关键词： Electrical stimulation     Biodegradation     Microbial community     Chloramphenicol    

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Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting

Wenfu Xie, Zhenhua Li, Mingfei Shao, Min Wei

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 537-554 doi: 10.1007/s11705-018-1719-6

摘要：

Electrochemical water splitting is an efficient and clean strategy to produce sustainable energy productions (especially hydrogen) from earth-abundant water. Recently, layered double hydroxide (LDH)-based materials have gained increasing attentions as promising electrocatalysts for water splitting. Designing LDHs into hierarchical architectures (e.g., core-shell nanoarrays) is one of the most promising strategies to improve their electrocatalytic performances, owing to the abundant exposure of active sites. This review mainly focuses on recent progress on the synthesis of hierarchical LDH-based core-shell nanoarrays as high performance electrocatalysts for electrochemical water splitting. By classifying different nanostructured materials combined with LDHs, a number of LDH-based core-shell nanoarrays have been developed and their synthesis strategies, structural characters and electrochemical performances are rationally described. Moreover, further developments and challenges in developing promising electrocatalysts based on hierarchical nanostructured LDHs are covered from the viewpoint of fundamental research and practical applications.

关键词： layered double hydroxides (LDHs)     core-shell nanoarrays     oxygen evolution reaction (OER)     hydrogen evolution reaction (HER)     photoelectrochemical water splitting (PEC)    

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Strategic Thinking on Shallow-water Oil and Gas Exploration in Offshore China

Ke-qiang Wu,Jian-yong Xu,Bo Kang

《工程管理前沿（英文）》 2016年 第3卷 第4期   页码 349-355 doi: 10.15302/J-FEM-2016056

摘要： The oil and gas exploration in offshore China has made great achievements, and as the important areas of offshore exploration, the shallow waters contribute most of the oil and gas reserves and production. However, the available area for exploration is diminishing and the cost of exploration is rising. The field changes and ever increasing difficulties of exploration bring new challenges technically and economically. Therefore, for effective exploration of shallow-water oil and gas in offshore China, it is necessary to center on the general requirements of becoming a powerful marine country and the ideas of value exploration, initiate key research projects in the fields of China’s offshore stratigraphic-lithologic reserves, Paleogene reserves, buried-hill reserves, high temperature and pressure reserves and hydrocarbon-rich sags, and form geological theories and explorative technologies of large and medium size oil and gas field in offshore China. The measures regarding the challenges include: (1) Innovating theoretical understanding and optimizing new exploration fields, (2) developing technical capabilities and improving the success rate of exploration, and (3) enhancing management level and deepening value exploration.

关键词： offshore China     shallow-water oil and gas exploration     strategic thinking     challenge     countermeasure    

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南海北部深水区油气勘探进展与未来展望

米立军 ,周守为 ,谢玉洪 ,张功成 ,杨海长

《中国工程科学》 2022年 第24卷 第3期   页码 58-65 doi: 10.15302/J-SSCAE-2022.03.007

摘要：

加大油气勘探开发力度，减少石油和天然气对外依存度，保障国家能源安全是关系国家经济社会发展的全局性、战略性问题。“十一五”以来，中国海洋石油集团有限公司在南海北部深水领域持续加强基础研究，加快技术创新和加大勘探投入，相继获得一批重大油气勘探发现。本文阐述了五项重大勘探地质理论认识和两项勘探技术创新成果，探讨了深水油气勘探将要面临的挑战和应对策略，展望了南海北部深水区中深层、潜山及岩性圈闭三大领域的勘探前景。研究指出，南海北部陆缘深水区的拆离作用控制了珠江口盆地和琼东南盆地大型凹陷的形成，发育了湖相、海陆过渡相和海相三套规模烃源岩；高‒ 变地温控制凹陷烃源岩快速生烃，建立了琼东南盆地深水区大型轴向峡谷水道油气成藏模式、白云凹陷深水区深水扇天然气晚期成藏模式和深水区“断‒ 脊”联控油气差异聚集成藏模式。同时自主创新研发了立体震源激发和“犁形”缆接收的宽频采集处理技术。在多项地质理论认识和创新技术的指导下，发现以“深海一号”（陵水17-2）等为代表的一批大中型气田，对于保障粤港澳大湾区能源供应、促进海南自贸区（港）能源绿色发展、推动我国油气增储上产具有重要意义。

关键词： 南海北部；深水区；油气勘探；深水天然气    

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Coordinated shift control of nonsynchronizer transmission for electric vehicles based on dynamic tooth

《机械工程前沿（英文）》 2021年 第16卷 第4期   页码 887-900 doi: 10.1007/s11465-021-0653-3

摘要： Multispeed transmissions can enhance the dynamics and economic performance of electric vehicles (EVs), but the coordinated control of the drive motor and gear shift mechanism during gear shifting is still a difficult challenge because gear shifting may cause discomfort to the occupants. To improve the swiftness of gear shifting, this paper proposes a coordinated shift control method based on the dynamic tooth alignment (DTA) algorithm for nonsynchronizer automated mechanical transmissions (NSAMTs) of EVs. After the speed difference between the sleeve (SL) and target dog gear is reduced to a certain value by speed synchronization, angle synchronization is adopted to synchronize the SL quickly to the target tooth slot’s angular position predicted by the DTA. A two-speed planetary NSAMT is taken as an example to carry out comparative simulations and bench experiments. Results show that gear shifting duration and maximum jerk are reduced under the shift control with the proposed method, which proves the effectiveness of the proposed coordinated shift control method with DTA.

关键词： electric vehicle     nonsynchronizer automated mechanical transmission (NSAMT)     planetary gear     coordinated shift control     dynamic tooth alignment    

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标题 作者 时间 类型 操作

Enhanced activity of bimetallic Fe-Cu catalysts supported on ceria toward water gas shift reaction: synergistic

期刊论文

Catalytic performance of Co-Mo-Ce-K/γ-Al

Yuqiong ZHAO, Yongfa ZHANG

期刊论文

Effect of adjusted mesoscale drag model on flue gas desulfurization in powder-particle spouted beds

期刊论文

Seasonal microbial community shift in a saline sewage treatment plant

Qingmei YAN, Xuxiang ZHANG, Tong ZHANG, Herbert H P FANG

期刊论文

Potential shift of bacterial community structure and corrosion-related bacteria in drinking water distributionpipeline driven by water source switching

Yue Hu, Ding Dong, Kun Wan, Chao Chen, Xin Yu, Huirong Lin

期刊论文

Kinetics of pozzolanic reaction for preparation of flue gas desulfurizer from fly ash and Ca(OH)2

WANG Jingang, HU Jinbang, WANG Daobin, DUAN Zhenya

期刊论文

NO conversion by positive streamer discharge—effects of gas compositions and reaction conditions

HE Wei, ZHU Tianle, LI Jing

期刊论文

route to achieve MoSe-NiSe on nickel foam as efficient dual functional electrocatalysts for overall water

期刊论文

Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

期刊论文

Modified landfill gas generation rate model of first-order kinetics and two-stage reaction

Jiajun CHEN , Hao WANG , Na ZHANG ,

期刊论文

The impact of different voltage application modes on biodegradation of chloramphenicol and shift of microbial

期刊论文

Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting

Wenfu Xie, Zhenhua Li, Mingfei Shao, Min Wei

期刊论文

Strategic Thinking on Shallow-water Oil and Gas Exploration in Offshore China

Ke-qiang Wu,Jian-yong Xu,Bo Kang

期刊论文

南海北部深水区油气勘探进展与未来展望

米立军 ,周守为 ,谢玉洪 ,张功成 ,杨海长

期刊论文

Coordinated shift control of nonsynchronizer transmission for electric vehicles based on dynamic tooth

期刊论文